CSA Unit 1 - Safety

Chapter 3: Hazardous Materials in the Gas Industry

A comprehensive learning module covering the Workplace Hazardous Materials Information System (WHMIS) 2015, safety procedures, and best practices for handling hazardous materials in the gas industry.

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Learning Objectives

By the end of this module, you will be able to:

  • Understand WHMIS 2015: Describe the Workplace Hazardous Materials Information System
  • Know Safety Procedures: Describe safe handling, storage, disposal, and transportation of hazardous materials
  • Apply Knowledge: Use this information to work safely with hazardous materials in the gas industry

โš ๏ธ Important Safety Notice

In the gas industry, technicians and fitters are exposed to a variety of potentially toxic and explosive materials. Federal and provincial legislation provides for the gas technician's/fitter's right to know about major risks and required safety protection measures.

Knowledge Check 1: Learning Objectives

What does WHMIS stand for?

Workplace Health Management Information System
Workplace Hazardous Materials Information System
Workplace Hazard Monitoring Information System
Workplace Health and Materials Information System

WHMIS 2015 Overview

What is WHMIS 2015?

The Workplace Hazardous Materials Information System (WHMIS) was established in 1988 and updated through legislation in 2015. It provides workers, employers, and suppliers of materials with vital information about hazardous materials in the workplace.

Global Alignment

WHMIS 2015 aligns with the Globally Harmonized System of Classification and Labelling of Chemicals (GHS), created by the United Nations. This international standardization ensures consistent hazard communication worldwide.

Essential Understanding for Gas Technicians/Fitters

Gas technicians and fitters must understand their rights and responsibilities relating to WHMIS 2015 and maintain good housekeeping practices to ensure safety.

WHMIS 2015 Legislation

โœ… Federal Legislation

Deals with the importation and sale of controlled products. This includes establishing criteria for including hazardous products and requirements for suppliers to provide appropriate labels and SDS.

๐Ÿ›๏ธ Provincial Legislation

Concerned with the storage, handling, and use of hazardous products in the workplace. Through amendments to Occupational Safety and Health Regulations, ensures employers provide worker education and training.

Knowledge Check 2: WHMIS 2015

WHMIS 2015 aligns with which international system?

International Safety Standards (ISS)
Globally Harmonized System (GHS)
World Health Organization Standards
International Chemical Safety System

GHS Terminology

Key GHS Terms

Hazard Group

Physical hazards group: Based on physical or chemical property

Health hazards group: Based on the health effect of the product

Hazard Class

Products that have similar hazardous properties.

Examples: Flammable gases, oxidizing liquids, gases under pressure, acute toxicity, aspiration hazard

Hazard Category

How hazardous the product is.

Examples: Category 1, 1B, 2, 2A, etc.

Knowledge Check 3: GHS Terminology

Which GHS term describes how hazardous a product is?

Hazard Group
Hazard Class
Hazard Category
Hazard Type

Labels and Safety Data Sheets (SDS)

GHS Label Elements

๐Ÿ”ฃ Symbols

GHS hazard pictograms - visual symbols that quickly identify hazard types

โš ๏ธ Signal Words

"Danger" for more severe hazards
"Warning" for less severe hazards
Only one signal word appears on a label

๐Ÿ“‹ Hazard Statements

Brief, standardized statements to describe the product's hazards. Includes phrases assigned to a hazard class and category.

๐Ÿ›ก๏ธ Precautionary Statements

Focus on "general", "prevention", "response", "storage", and "disposal" information on how to minimize or prevent harmful effects.

Types of Labels

Supplier Label
  • Provided or affixed by the supplier
  • Appears on all hazardous products received in Canada
  • No other label required if product always used in original container
Workplace Label

Required when:

  • Hazardous product is produced at the workplace
  • Product is decanted into another container
  • Supplier label becomes lost or illegible

Safety Data Sheets (SDS)

SDS evolved from Material Safety Data Sheets (MSDS) under WHMIS 2015. They are more detailed than labels and provide comprehensive hazard information.

SDS Update Requirements

SDS are updated when suppliers make significant changes. These changes must be communicated as soon as possible to consumers. SDS contain 16 information sections, with sections 12-15 optional for suppliers.

Section 1: Identification

Product identifier, supplier info, emergency phone number

Section 2: Hazard Identification

Hazard classification, label elements, other hazards

Section 3: Composition

Chemical name, CAS number, concentration

Section 4: First-aid Measures

By route of exposure, symptoms, medical attention

Section 5: Fire-fighting Measures

Extinguishing media, specific hazards, protective equipment

Section 6: Accidental Release

Personal precautions, containment, cleanup methods

Section 7: Handling and Storage

Safe handling precautions, storage conditions

Section 8: Exposure Controls/PPE

Control parameters, engineering controls, protection measures

Knowledge Check 4: Labels and SDS

How many sections does a complete SDS contain?

12 sections
14 sections
16 sections
18 sections

WHMIS 2015 Hazard Pictograms

Understanding Pictograms

Hazard pictograms are symbols with red borders in a diamond shape that easily and visibly identify products by hazard group, hazard class, and hazard category. Pictograms display on labels and SDS.

๐Ÿ”ฅ
Flammable

Flammable gases, liquids, solids; pyrophoric materials; self-heating substances; organic peroxides

๐Ÿ”ด
Oxidizing

Oxidizing gases, liquids, and solids (categories 1, 2, 3)

๐Ÿ’€
Toxic

Acute toxicity (oral, dermal, inhalation) categories 1, 2, 3

๐Ÿงช
Corrosive

Corrosive to metals; skin corrosion/irritation; serious eye damage

๐Ÿ’ฅ
Explosive

Self-reactive substances and mixtures, organic peroxides (types A, B)

โš ๏ธ
Health Hazard

Carcinogenicity, mutagenicity, reproductive toxicity, respiratory sensitization

โ—
Exclamation Mark

Acute toxicity (category 4), skin/eye irritation, respiratory sensitization

๐Ÿงฌ
Biohazardous

Biohazardous infectious materials that can cause diseases in people or animals

โš™๏ธ
Compressed Gas

Compressed gases, liquefied gases, refrigerated liquefied gases, dissolved gases

Knowledge Check 5: Pictograms

Which pictogram would you find on containers of propane gas?

Toxic (skull and crossbones)
Flammable and Compressed Gas
Corrosive
Explosive

Liquid Solvents, Glues, and Resins

What are Solvents?

Solvents are liquids that dissolve other substances. They are used as cleaning agents to dissolve oils, greases, and resins, and in the production of paints, lacquers, adhesives, and cements for plastic and fibreglass.

โš ๏ธ Health Risks

Exposure to solvents may present a permanent threat to your health and reduce your awareness, thereby increasing the potential for mistakes and accidents.

Methods of Solvent Exposure

๐Ÿซ Inhalation

Excessive breathing of solvent vapours affects the central nervous system, causing dizziness, nausea, headaches, sleepiness, unconsciousness, and possibly death. Can cause serious damage to blood, lungs, liver, and kidneys.

โœ‹ Skin Contact

All solvents can dry and irritate skin with continuous contact, leaving skin subject to disabling dermatitis and opening the way to serious infection. Many solvents are easily absorbed through skin.

๐Ÿ‘„ Ingestion

Accidental swallowing of industrial solvents is rare because of their unpleasant odour that usually identifies them.

Safety Precautions for Handling Liquid Solvents

โœ… DO
  • Use only approved containers in good condition
  • Keep containers tightly closed when not in use
  • Clean up liquid spills immediately
  • Check grounding of large drums containing flammable liquids
  • Avoid skin contact and practice proper personal hygiene
  • Always use personal protective equipment (PPE)
โŒ DO NOT
  • Use a container for any liquid other than its intended purpose
  • Use sawdust to absorb spills unless you can immediately dispose of it safely
  • Smoke or produce sparks near flammable liquids
  • Work with a solvent if you're unsure of its properties

Storage of Liquid Solvents

๐Ÿ“ Storage Location

Solvents may be stored in above-ground or underground tanks. Outside storage is preferred, but drums should be protected from direct sunlight and heat sources.

๐Ÿšซ No Smoking or Eating

Do not smoke or eat in any area where solvents or volatile substances are stored or used. Risk of fire from sparks or food contamination is extreme.

๐Ÿท๏ธ Clear Labeling

Contents of each drum should be clearly labelled to prevent accidents from improper use or incorrect mixtures. Include handling precautions and emergency actions.

Knowledge Check 6: Liquid Solvents

What is the most dangerous route of solvent exposure?

Skin contact
Inhalation
Ingestion
Eye contact

Toxic Materials in the Gas Industry

Categories of Toxic Materials

๐Ÿงช Chemical Solvents, Glues, and Resins

Gas technicians use various products to join fittings for plastic pipe in venting systems. Solvents and glues used with ABS, PVC, and CPVC products are toxic. Special PPE required in unventilated or confined spaces.

โ˜ข๏ธ Chlorine

Non-flammable, strong oxidant with disagreeable, suffocating odour. Strong eye and lung irritant. Exposure to 15-30 ppm causes burning sensation in eyes, nose, and throat.

๐Ÿ—๏ธ Asbestos

One of the most dangerous substances. Designated substance that must be reported to employer. Microscopic fibres can cause permanent lung damage. Requires certified training for handling.

๐Ÿ’จ Sewer Gas

Mixture of vapours including methane, hydrogen sulfide, carbon monoxide. Some gases are combustible and explosive. Testing required before entering sewers.

โšก Metal Fumes

Zinc or cadmium fumes from cutting galvanized materials with oxyacetylene torch produce highly toxic, dense white smoke. Requires proper ventilation or breathing equipment.

Chlorine Exposure Effects

๐Ÿซ Respiratory Effects

Affects upper and lower respiratory tract. Symptoms include eye and throat irritation, choking, restlessness, nausea, vomiting, shortness of breath, chest pain, and fluid in lungs.

๐Ÿ’€ Severe Exposure

Brief exposure to very high concentrations (800 ppm) may cause death from suffocation. Skin or eye contact causes severe local irritation and burns.

๐Ÿ”ฅ Combustion Properties

While not explosive or flammable, chlorine supports combustion. Water in certain concentrations is explosive with chlorine gas when ignited by a spark.

Asbestos Safety Precautions

Certified Training

Personnel working with asbestos removal must successfully complete a certified asbestos abatement course.

Authority Contact

Must contact the authority having jurisdiction (typically Ministry of Labour) before removing asbestos.

Proper Protection

Always use appropriate respiratory protection and protective clothing when working with asbestos.

Decontamination

Follow proper decontamination procedures after working with asbestos materials.

Knowledge Check 7: Toxic Materials

What concentration of chlorine exposure can cause death from suffocation?

100 ppm
400 ppm
800 ppm
1200 ppm

Common Fuel Gases

Types of Fuel Gases

โ›ฝ Gasoline

Liquid fuel used primarily in vehicles and small engines. Designed to ignite easily, making it extremely dangerous.

๐Ÿš› Diesel

Liquid fuel used in diesel engines and heating systems. Less volatile than gasoline but still hazardous.

๐Ÿ”ด Propane (LP-gas)

Liquefied petroleum gas used for heating, cooking, and vehicles. Heavier than air (density 1.5), collects in low areas.

๐Ÿ”ต Natural Gas

Gaseous fuel distributed through pipeline systems. Lighter than air (density 0.6), rises and disperses.

LP-gas and Natural Gas Properties

Both fuels are non-toxic and should not harm anyone breathing low concentrations near minor leaks. In pure states, both are tasteless, colourless, and odourless. Mercaptan is added as a safety measure so they can be detected at 1% atmospheric concentration.

โš ๏ธ Dangerous Mixtures

The combination of LP-gas or natural gas and oxygen produces an extremely dangerous mixture. If a leak is suspected, immediately shut off the supply at its source and check for leaks with an approved testing agent.

Gas Density Characteristics

๐Ÿ”ต Natural Gas (Lighter than Air)

Relative density 0.6 - rises and is dissipated by air currents. Tends to accumulate near ceilings and upper areas.

๐Ÿ”ด Propane (Heavier than Air)

Relative density 1.5 - descends and collects in low points. Invisible pockets can remain ready to ignite from spark sources like electrical switches.

Safety Precautions for Gasoline and Diesel

๐Ÿšซ No Smoking

Smoking prohibited while working with fuel gases. Gasoline's flammable limits are 1%-16%.

๐Ÿงฝ Not for Cleaning

Never use gasoline and diesel as cleaning agents. Use proper solvents designed for cleaning.

โšก Prevent Sparks

When transferring fuels, avoid sparks that may cause ignition. Ensure proper grounding.

๐Ÿงน Clean Spills Properly

Place cleanup materials in designated, sealed containers. Never use sawdust unless immediately disposable.

Transportation Requirements

๐Ÿ“ฆ Approved Containers

Transport and store in approved containers bearing CSA or ULC labels. Ensure containers are not damaged and properly secured.

๐Ÿš— Vehicle Transport

Never carry gasoline and flammable liquids in passenger compartment. Transport upright, braced, or otherwise secured.

๐Ÿงฏ Fire Extinguisher

Keep ABC fire extinguisher in driver's compartment while transporting gasoline or flammable liquids in a van.

Knowledge Check 8: Fuel Gases

Which fuel gas is heavier than air and collects in low areas?

Natural Gas
Propane
Methane
Hydrogen

Safety Procedures and Good Housekeeping

Worker Rights and Responsibilities

โœ… Worker Rights
  • Right to know about hazards in the workplace
  • Right to access up-to-date SDS information
  • Right to proper training on hazardous materials
  • Right to appropriate personal protective equipment
๐Ÿ“‹ Worker Responsibilities
  • Participate in education and training programs
  • Use information to work safely with hazardous products
  • Report missing or illegible labels
  • Notify supervisors of additional precautions needed
  • Follow proper handling, storage, and disposal procedures

Employer Responsibilities

๐Ÿ“š Education & Training

Establish education and training programs for workers exposed to hazardous products

๐Ÿท๏ธ Labeling

Ensure all hazardous products are properly labeled

๐Ÿ“„ SDS Availability

Maintain current SDS for each hazardous product

๐Ÿ‘๏ธ Accessibility

Make labels and SDS readily available to workers

Good Housekeeping Practices

Follow Proper Procedures

The responsibility of a gas technician/fitter is to follow proper handling, storage, and use requirements for hazardous materials.

Consult SDS

Consult the SDS provided by the employer and ensure you have the most recent updates to these sheets.

Read Manufacturer Instructions

Ensure you read and follow directions on manufacturers' information sheets when handling hazardous products.

Seek Help When Needed

If information on proper handling is not available, contact your area's Construction Safety Association for help.

Consult Supervisor

If you cannot obtain needed information, consult your supervisor before using any product to ensure you are completely informed.

Knowledge Check 9: Safety Procedures

Who is responsible for establishing education and training programs for hazardous materials?

Workers
Employers
Suppliers
Government

Emergency Response and First Aid

Emergency Response Procedures

Identify the Hazard

Consult labels and SDS to understand the specific hazards of the material involved.

Protect Yourself and Others

Use appropriate PPE and evacuate unnecessary personnel from the area.

Contain the Hazard

For spills, use appropriate containment methods as specified in the SDS.

Report the Incident

Notify supervisors and appropriate emergency response personnel.

Document the Incident

Record all details of the incident and response actions taken.

Spill Cleanup Procedures

๐Ÿšจ Alert

Notify others in the area about the spill

๐Ÿ›ก๏ธ Protect

Put on appropriate PPE before approaching the spill

๐Ÿ“ฆ Contain

Use appropriate materials to prevent spreading

๐Ÿงน Clean

Use proper absorbents and disposal containers

๐Ÿ“ Report

Document the incident according to workplace procedures

First Aid for Hazardous Materials Exposure

๐Ÿซ Inhalation

Move victim to fresh air. If breathing is difficult, administer oxygen if available and trained to do so. Seek medical attention immediately.

โœ‹ Skin Contact

Remove contaminated clothing. Flush affected area with water for at least 15 minutes. For chemical burns or persistent irritation, seek medical attention.

๐Ÿ‘๏ธ Eye Contact

Flush eyes with water for at least 15 minutes, holding eyelids open. Remove contact lenses if present. Seek medical attention immediately.

๐Ÿ‘„ Ingestion

Do not induce vomiting unless directed by medical personnel. If conscious, rinse mouth with water. Seek immediate medical attention.

Hazardous Waste Disposal

๐Ÿงช Liquid Solvents and Glues

Must be disposed of in approved containers through licensed hazardous waste disposal companies. Never pour down drains or sewers.

๐Ÿงฝ Contaminated Materials

Rags, absorbents, and other materials contaminated with hazardous substances must be placed in designated containers and disposed of as hazardous waste.

๐Ÿ“ฆ Empty Containers

Even empty containers that held hazardous materials must be handled according to regulations. Some may be recycled after proper cleaning.

๐Ÿ—๏ธ Asbestos Materials

Must be wetted, double-bagged in specially marked bags, and disposed of only at facilities licensed to accept asbestos waste.

Knowledge Check 10: Emergency Response

For how long should you flush eyes that have been exposed to hazardous chemicals?

5 minutes
10 minutes
15 minutes
20 minutes

๐ŸŽ“ Module Completion Certificate

Congratulations! You have successfully completed

CSA Unit 1 Safety - Chapter 3: Hazardous Materials in the Gas Industry

You now have the knowledge and skills to work safely with hazardous materials in accordance with WHMIS 2015 requirements.

Summary of Key Learning Points

๐Ÿ“š Knowledge

Understanding WHMIS 2015 and hazardous materials properties

๐Ÿ›ก๏ธ Protection

Using appropriate PPE and safety measures

๐Ÿ“‹ Procedures

Following proper handling, storage, and disposal methods

๐Ÿšจ Emergency Response

Knowing what to do in case of exposure or spills

๐Ÿ“– Continuous Learning

Staying updated on regulations and best practices

Information Resources

๐Ÿฅ Canadian Centre for Occupational Health and Safety

Visit www.ccohs.ca for more information on chlorine and other hazardous materials.

๐Ÿš› Transport Canada

For Transportation of Dangerous Goods (TDG) information: http://www.tc.gc.ca/eng/tdg/safety-menu.htm

๐Ÿ“‹ CSA Standards

Reference CSA B149.2, CSA B340, and CSA-B622 for transportation requirements.

๐Ÿ›๏ธ Provincial Resources

WHMIS 2015 leaflets available through provincial Workers Compensation Board or Workers Safety Insurance Board.

Final Assessment: Comprehensive Review

1. Which pictogram would indicate a product that can cause cancer?

Exclamation mark
Health hazard (human silhouette)
Toxic (skull and crossbones)
Corrosive

2. What is the first step when responding to a hazardous material spill?

Begin cleanup immediately
Call emergency services
Identify the hazard using labels and SDS
Evacuate the building

3. Which fuel gas is heavier than air and requires special ventilation considerations?

Natural gas
Propane
Methane
Hydrogen

4. What does SDS stand for in WHMIS 2015?

Standard Data Sheet
Safety Data Sheet
Supplier Data Sheet
Substance Data Sheet

5. Which exposure route for solvents affects the central nervous system most directly?

Skin contact
Inhalation
Eye contact
Ingestion